SPECTRUM CHEMICAL MANUFACTURING CORP -- SODIUM HYDROXIDE -- 6810-00-174-6585
===================== Product Identification ===================== Product ID:SODIUM HYDROXIDE MSDS Date:06/01/1997 FSC:6810 NIIN:00-174-6585 Status Code:A === Responsible Party === Company Name:SPECTRUM CHEMICAL MANUFACTURING CORP Address:14422 S SAN PEDRO ST City:GARDENA State:CA ZIP:90248-2027 Country:US Info Phone Num:714-864-2310 (CHEMICAL COMMODITIES) Emergency Phone Num:800-772-8786 Preparer's Name:CHARLES A EISENHARD CAGE:63415 === Contractor Identification === Company Name:CHEMICAL COMMODITIES AGENCY, INC. Address:27447 PACIFIC STREET Box:City:HIGHLAND State:CA ZIP:92346-2640 Country:US Phone:909-864-2310 CAGE:60777 Company Name:SPECTRUM LABORATORY PRODUCTS INC Address:14422 S SAN PEDRO ST Box:City:GARDENA State:CA ZIP:90248-2027 Country:US Phone:310-516-8000/FAX: 310-516-9843 CAGE:63415 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM HYDROXIDE (SARA III) CAS:1310-73-2 RTECS #:WB4900000 Fraction by Wt: 100% OSHA PEL:2 MG/M3 ACGIH TLV:C 2 MG/M3; 9394 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHALED:200 MG NAOH/M3=IDLH. MIST= RESPIRATORY TRACT DAMAGE;MILD IRRITATION TO SEVERE PNEUMONITIS. CHRONIC: BRONCHIAL PNEUMONIA, G/I DISTURBANCE. SKIN:25-50% = IRRITATION W/IN 3 MIN. IF NNOT REMOVED; SEVERE DEEP ULCERATION. CHRONIC:DERMATITIS. EYE: DISINTEGRATION & SLOUGHING OF EPITHELIUM. CONTINUED IN SIGNS & SYMPTOMS Explanation of Carcinogenicity:MANUFACTURER GAVE NO COMMENTS OTHER THAN THE ABOVE REFERENCES TO THE THREE LISTINGS. Effects of Overexposure:CORNEAL OPACIFICATION, EDEMA & ULCERATION. CHRONIC:CONJUNCTIVITIS. INGESTED:SEVERE ABDOMINAL PAIN, CORROSION OF UPPER MOUTH AREA. VOMITING PIECES OF MUCOSA ASPHYXIA DUE TO SWELLING OF THROAT. PERFORAT ION OF ESOPHAGAS & STOMACH MAY OCCUR. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALED:IF BREATHING STOPPED GIVE ARTIFICIAL RESPIRATION,GET IMMEDIATE MEDICAL ATTENTION. SKIN:REMOVE CONTAMINATED CLOTHING. WASH AREA W/SOAP & WATER FOR 15 MIN. APPLY STERILE BANDAGES & SECURE. EYES: FLUSH W/COPIOUS AMT WATER FOR 15 MIN. GET IMMEDIATE MEDICAL ATTENTION. INGESTED:DO NOT USE GASTRIC LAVAGE OR EMISIS. DILUTE W/WATER OR MILK. ALLOW VOMITING TO OCCUR. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NEGLIGIBLE Autoignition Temp:Autoignition Temp Text:NONE Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, HALON, WATER SPRAY OR STANDARD. Fire Fighting Procedures:MOVE CONTAINERS FROM FIRE AREA IF POSSIBLE. COOL CONTAINERS EXPOSED TO FLAME W/WATER FROM SIDE UNTIL WELL AFTER FIRE IS OUT. USE AGENT SUITABLE FOR TYPE OF FIRE Unusual Fire/Explosion Hazard:USE FLOODING QUANTITIES OF WATER AS FOG, APPLY FROM AS FAR A DISTANCE AS POSSIBLE. AVOID BREATHING CORROSIVE VAPORS. KEEP UP WIND. ================== Accidental Release Measures ================== Spill Release Procedures:DO NOT TOUCH SPILLED MATERIAL.STOP LEAK IF W/O RISK. TAKE UP W/SAND OR OTHER ABSORBENT MATERIAL & PLACE IN DOT APPROVED CONTAINERS. SOIL:DIC A HOLDING AREA TO CONTAIN THE SPILL. AIR SPILL:KNOCK DOWN V APORS W/WATER SPRAY. WATER:NEUTRALIZE W/DIL. ACID. Neutralizing Agent:ADD AGENT TO NEUTRALIZE SPILLED MATERIAL TO PH7. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A DRY PLACE, PROTECT AGAINST MOISTURE AND WATER, SEPERATE FROM ACIDS, METALS, EXPLOSIVES, ORGANIC PEROXIDES & EASILY IGNITABLE MATERIALS. Other Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SUPPLIED AIR RESPIRATOR OPERATED IN THE POSITIVE PRESSURE MODE. Ventilation:LOCAL EXHAUST OR PROCESS ENCLOSURE VENTILATION. Protective Gloves:IMPERVIOUS Eye Protection:SPLASH/DUST RESSSISTANT SAFETY GOGGLES Other Protective Equipment:IMPERVIOUS CLOTHING, EYE WASH STATION AND SAFETY SHOWER, Work Hygienic Practices:WASH THOROUGHLY BEFORE EATING OR DRINKING. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:B1 NRC/State Lic Num:NONE Boiling Pt:B.P. Text:253F,123C Melt/Freeze Pt:M.P/F.P Text:604F,318C Vapor Pres:100MM Spec Gravity:2.130 Solubility in Water:MISCIBLE Appearance and Odor:COLORLESS, WHITE OR OFF WHITE HYGROSCOPIC SOLID OR PELLET FORM. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALDEHYDE, ACETIC ACID, ACROLEIN, ACRYLONITRILE, ALUMINUM, HYDROFLUORIC ACID, NITROMETHANE, FOOD SUGARS, WATER. Stability Condition to Avoid:REACTS EXOTHERMICALLY WITH WATER. Hazardous Decomposition Products:MAY RELEASE TOXIC FUMES OF SODIUM OXIDE. Conditions to Avoid Polymerization:MAY CAUSE VIOLENT POLYMERIZATION OF ACETALDEHYDE, ACROLEIN, OR ACRYLONITRILE. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTACT YOUR DISTRICT DIRECTOR OF THE EPA TO ACSCERTAIN PROPER DISPOSAL INFORMATION. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.