MALLINCKRODT INC -- POTASSIUM PERMANGANATE -- 6810-00F032013
===================== Product Identification ===================== Product ID:POTASSIUM PERMANGANATE MSDS Date:04/06/1992 FSC:6810 NIIN:00F032013 === Responsible Party === Company Name:MALLINCKRODT INC Address:PARIS BYPASS Box:800 City:PARIS State:KY ZIP:40362 Country:US Info Phone Num:314-539-1600 Emergency Phone Num:314-539-1600 CAGE:62910 === Contractor Identification === Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:908-859-2151 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:POTASSIUM PERMANGANATE CAS:7722-64-7 RTECS #:SD6475000 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): 1090 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHALATION: IRRITATION TO NASAL/RESPIRATORY PASSAGES. SKIN: SEVERE IRRITATION/DEFATTING, DERMATITIS. EYES: IRRITATION. INGESTION: IRRITATING TO THE GI SYSTEM. CHRONIC MANGENESE POISONING MAY CAUSE IMP AIRMENTS OF CNS. Explanation of Carcinogenicity:NONE Effects of Overexposure:INGESTION: NAUSEA, VOMITING, DIARRHEA. SKIN: REDNESS, PAIN, BURNS. EYES: REDNESS, TEARING. MANGANESE POISONING: SLUGGISHNESS, SLEEPINESS, WEAKNESS IN THE LEGS, FIXED FACIAL EXPRESSION, EMOTIONAL DISTU RBANCES, GASTRIC GAIT, FALLING. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. INGESTION: INDUCE VOMITING IMMEDIATELY BY GIVING TWO GLASSES OF WATER/MILK IF AVAILABLE/STICKING FINGER DOWN THROAT. SKIN: FLUSH W/PLENTY OF WATER & SOAP FOR 15 MINUTE S WHILE REMOVING CONTAMINATED CLOTHING/SHOES. EYES: WASH W/PLENTY OF WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER SPRAY TO BLANKET FIRE, COOL FIRE EXPOSED CONTAINERS & TO FLUSH NON-IGNITED SPILLS/VAPORS AWAY FROM FIRE. Fire Fighting Procedures:FULL PPROTECTIVE CLOTHING & NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS W/FULL FACEPIECE OPERATED IN THE PRESSURE DEMAND/OTHER POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:SUBSTANCE IS A STRONG OXIDIZER & ITS HEAT/SHOCKED OF REACTION W/REDUCING AGENTS/COMBUSTIBLES MAY CAUSE IGNITION/EXPLOSION. ACTS AS DUST EXPLOSION. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE CLOTHING/EQUIPMENT SUITABLE FOR FLAMMABLE/FIRE PROMOTING MATLS. DIKE/COVER SPILL W/FERROUS SULFATE/SODIUM SULFIT/SODIUMTHIOSULFATE, THEN MOISTEN/ACIDIFY IF NECESSARY TO PROMOTE REDUCTI ON REACTION. NEUTRALIZE. Neutralizing Agent:SODA ASH ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A TIGHTLY CLOSED CONTAINER. STORE IN A COOL, DRY, WELL VENTILATED AREA AWAY FROM HEAT & IGNITION SOURCES. Other Precautions:DON'T STORE ON WOODEN FLOORS. DON'T WEAR CONTACT LENSES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV IS EXCEEDED, USE A DUST/MIST RESPIRATOR UP TO 18 TIMES THE TLV. Ventilation:LOCAL/GENERAL EXHAUST Protective Gloves:IMPERVIOUS Eye Protection:CHEMICAL SAFETY GOGGLES/FULL FACE SHIELD Other Protective Equipment:EYE WASH FOUNTAIN, BOOTS, LAB COAT, APRON, COVERALLS, QUICK DRENCH FACILITIES. Work Hygienic Practices:REMOVE CONTAMINATED CLOTHING & SHOES. WASH BEFORE REUSE. Supplemental Safety and Health DENSITY: 2.7 MATERIALS TO AVOID CON'T: HYDRIDES, STRONG HYDROGEN PEROXIDE, FERROUS OR MERCUROUS SALTS, HYPOPHOSPHITES, HYPOSULFITES, SULFITES, PEROXIDES & OXALATES. ================== Physical/Chemical Properties ================== Decomp Temp:Decomp Text:464F Solubility in Water:COMPLETE Appearance and Odor:PURPLE BRONZE CRYSTAL W/NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES POWDERED METALS/ALCOHOL/ARSENITES/BROMIDES/IODIDESPHOSPHOROUS/SULFURIC ACID/ORGANIC COMPOUNDS/SULFUR/ACTIVATE CARBON. Stability Condition to Avoid:HEAT, SHOCK, FRICTION & OTHER IGNITION SOURCES. Hazardous Decomposition Products:POSSIBLY TOXIC/IRRITATING OXIDES OF MANGANESE/POTASSIUM. ==================== Disposal Considerations ==================== Waste Disposal Methods:NEUTRALIZED WASTE MAY BE TRANSFERRED TO A CLOSED PREFERABLY METAL CONTAINER & SENT TO A RCRA-APPROVED WASTE DISPOSAL FACILITY IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.