SCIENCE KIT & BOREAL LABORATORIES -- AMMONIUM HYDROXIDE SOLUTION -- 6810-00-222-9643
===================== Product Identification ===================== Product ID:AMMONIUM HYDROXIDE SOLUTION MSDS Date:01/12/1987 FSC:6810 NIIN:00-222-9643 === Responsible Party === Company Name:SCIENCE KIT & BOREAL LABORATORIES Address:777 EAST PARK DRIVE City:TONAWANDA State:NY ZIP:14150-6784 Country:US Info Phone Num:716-874-6020 FAX: 716-874-9572 Emergency Phone Num:800-828-7777 Preparer's Name:ALEXANDER PICCIRILLI CAGE:57020 === Contractor Identification === Company Name:SCIENCE KIT INC Address:777 E PARK DR Box:City:TONAWANDA State:NY ZIP:14150-6708 Country:US Phone:716-874-6020 CAGE:57020 ============= Composition/Information on Ingredients ============= Ingred Name:AMMONIA (SARA 302/313) (CERCLA) (DISSOLVED IN WATER TO FORM AMMONIUM HYDROXIDE) CAS:7664-41-7 RTECS #:BO0875000 Fraction by Wt: 29% Other REC Limits:NONE RECOMMENDED OSHA PEL:50 PPM ACGIH TLV:25 PPM/35 STEL; 9495 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 71% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 350 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:CAUSES SEVERE IRRITATION OR BURNS TO EYES, SKIN AND MUCOUS MEMBRANES; HIGHLY TOXIC BY ORAL AND INHALATION ROUTES. INHALATION OF AMMONIA GAS CAUSES EDEMA, SPASM, AND ASPHYXIA. CHRONIC: NONE SPECIFIED B Y MANUFACTURER. Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN. Effects of Overexposure:INHALED-EDEMA, SPASM, ASPHIXIA. EYES-PAIN, BURNING, TEARS. SKIN-BURNS, REDNESS, PAIN. INGESTED-PAIN, BURNS TO MOUTH & THROAT, STOAMCH PAIN, NAUSEA, VOMITING. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN-FLOOD WITH WATER, THEN WASH WITH VINEGAR. EYES-FLUSH WITH LOTS OF WATER FOR AT LEAST 15 MINUTES. GET IMMEDIATE MEDICAL ATTENTION. INHALED-REMOVE TO FRESH AIR. RESTORE BRETAHING IF REQUIRED. GET M EDICAL ATTENTION. INGESTED-IF CONSCIOUS,GIVE LOTS OF WATER. FOLLOW WITH FRUIT JUICE AND VEGATABLE OIL. GET PROMPT MEDICAL ATTENION. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Lower Limits:16 Upper Limits:25 Extinguishing Media:USE ANY MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE GEAR. COOL FIRE EXPOSED CONTAINERS WITH WATER. Unusual Fire/Explosion Hazard:WHEN HEATED,EMITS TOXIC FUMES.AMMONIUM HYDROXIDE IS NON-COMBUSTIBLE & NON-EXPLOSIVE;BUT AMMONIA VAPORS RELEASED FROM SOLUTION CAN FORM AN EXPLOSIVE MIXTURE. ================== Accidental Release Measures ================== Spill Release Procedures:WEARING PROTECTIVE EQUIPENT, CAREFULLY NEUTRALIZE WITH SODIUM BISULFATE AND FLUSH TO SEWER WITH COPIOUS AMOUNTS OF WATER. NOTE: DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT TO LOCAL, STATE AND/OR F EDERAL REGULATIONS. Neutralizing Agent:SODIUM BISULFATE. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY AREA AWAY FROM ACIDS AND ACID FUMES OR OXIDIZING AGENTS. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. Other Precautions:READ LABEL ON CONTAINER BEFORE USING. FOR LABORATORY USE ONLY. NOT FOR FOOD, DRUG OR HOUSEHOLD USE. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR OR AN AIR-SUPPLIED RESPIRATOR OR SCBA, AS REQUIRED. USE IN ACCORDANCE WITH 29 CFR 1910.13 4 AND MANUFACTURER'S RECOMMENDATIONS. Ventilation:USE ADEQUATE MECHANICAL VENTILATION OR LOCAL EXHAUST TO MAINTAIN EXPOSURE BELOW TLV(S). Protective Gloves:RUBBER. Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES. Other Protective Equipment:GOGGLES, FACESHIELD, LAB COAT, APRON, VENTILATION HOOD, EYE WASH STATION. Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:B1 Boiling Pt:B.P. Text:212F,100C Melt/Freeze Pt:M.P/F.P Text:-107F,-77C Vapor Pres:584 MM HG Vapor Density:<1 Spec Gravity:0.896-0.902 Evaporation Rate & Reference:>1 (ETHER=1) Solubility in Water:COMPLETE Appearance and Odor:WATER, WHITE LIQUID; STRONG PUNGENT AMMONIA ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, ACROLEIN, DIMETHYL SULFATE, HALOGENS, SILVER NITRATE, SILVER PERMANGANATE. Stability Condition to Avoid:WHEN HEATED, EMITS TOXIC FUMES. Hazardous Decomposition Products:AMMONIA FUMES. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:WEARING PROPER PROTECTIVE CLOTHING, CAREFULLY NEUTRALIZE WITH SODIUM BISULFATE AND FLUSH TO SEWER WITH COPIOUS AMOUNTS OF WATER. DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT TO LOCAL, STAE AND/OR F EDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.