KUEHNE CHEMICAL CO -- SODIUM HYPOCHLORITE -- 6810-00N022069
===================== Product Identification ===================== Product ID:SODIUM HYPOCHLORITE MSDS Date:08/16/1993 FSC:6810 NIIN:00N022069 === Responsible Party === Company Name:KUEHNE CHEMICAL CO Address:86 HACKENSACK AVE City:SOUTH KEARNY State:NJ ZIP:07032 Country:US Info Phone Num:201-589-0700 Emergency Phone Num:201-589-0700 CAGE:0FK51 === Contractor Identification === Company Name:KUEHNE CHEMICAL CO INC Address:86 HACKENSACK AVE Box:City:SOUTH KEARNY State:NJ ZIP:07032 Country:US Phone:201-589-0700 CAGE:0FK51 ============= Composition/Information on Ingredients ============= Ingred Name:EYE PROT: & FULL LENGTH FACESHIELD . RTECS #:9999999ZZ Ingred Name:ING 17: REACH OF CHILDREN. RTECS #:9999999ZZ Ingred Name:ING 4: CLTHG BEFORE REUSE. INHAL: REMOVE TO FRESH AIR. IF BRTHG IS DFCLT HAVE TRAINED PERSON ADMIN OXYGEN. IF (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: RESPIRATION STOPS, GIVE MOUTH-TO-MOUTH RESUSCITATION. GET IMMED MED ATTN. INGEST: NEVER GIVE ANYTHING BY (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: MOUTH TO AN UNCON PERSON. IF SWALLOWED, DO NOT INDUCE VOMIT. GIVE LG QTYS OF MILK OR GELATIN SOLN; IF NOT (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: AVAIL, GIVE LG QTYS OF WATER. IF VOMIT OCCURS SPONT, KEEP AIRWAY CLEAR & GIVE MORE MILK, GELATIN SOLN OR (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: WATER. GET MED ATTN IMMED. AVOID VOMIT, LAVAGE OR ACIDIC ANTIDOTES. NOTE TO MD: SODIUM HYPOCHLORITE IS (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: ALKALINE CORR. FOR EXPOS BY INGEST DO NOT USE EMESIS, LAVAGE OR ACIDIC ANTIDOTES. DILUTE IMMED BY GIVING (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: MILK, MELTED ICE CREAM, BEATEN EGG WHITES, STARCH PASTE OR ANTACIDS SUCH AS MILK OF MAGNESIA, ALUMINUM (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: HYDROXIDE GEL OR MAGNESIUM TRISILICATE GEL. AVOID SODIUM BICARBONATE BECAUSE OF CARBON DIOXIDE RELS. (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: SODIUM THIOSULFATE SOLN MAY PROVE BENEFICIAL BY REDUCING UNREACTED MATERIAL. RTECS #:9999999ZZ Ingred Name:SPILL PROC: AQUATIC TOXICITY NOT ESTABLISHED, BUT BLEACH, IF NOT DILUTED, MAY SERIOUSLY AFFECT AQUATIC LIFE. RTECS #:9999999ZZ Ingred Name:OTHER PRECS: CNTNRS. ALL LABELED PRECAUTIONS MUST BE OBSERVED. DISPOSE OF CNTNR IN MANNER MEETING GOVT REGS. (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: PROD DISP:PROD SHOULD BE COMPLETELY REMOVED FROM CNTNRS. MATL THAT CANNOT BE USED/CHEMICALLY REPROCESSED(ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: SHOULD BE DISPOSED OF IN A MANNER MEETING FEDERAL, STATE & LOCAL GOVERNMENT REGULATIONS. KEEP OUT OF (ING 18) RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: CONTAMD CLTHG & SHES. CONTINUE TO FLUSH UNTIL MED ATTN ARRIVES. DISCARD NON-RUBBER SHOES. WASH (ING 5) RTECS #:9999999ZZ Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 85-86% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:HYPOCHLOROUS ACID, SODIUM SALT (CERCLA) CAS:7681-52-9 RTECS #:NH3486300 Fraction by Wt: 13-15% OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:SODIUM HYDROXIDE (CERCLA) CAS:1310-73-2 RTECS #:WB4900000 Fraction by Wt: 1% OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3, C EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL, RAT) 8910 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: CORROSIVE & STRONGLY IRRITATING TO EYES, SKIN & RESP TRACT. INHAL OF FUMES MAY CAUSE PULM EDEMA. INGEST MAY CAUSE BURNS TO MOUTH & DIGESTIVE TRACT. INHAL: HYPOCHLOROUS ACID FUMES MAY CAUSE SEVE RE RESP TRACT IRRIT & PULMONARY EDEMA. SKIN: CNTCT MAY CAUSE SEVERE IRRIT & BURNS. EYES: CNTCT MAY (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: CAUSE SEVERE IRRIT, BURNS &/OR CORROSION. INGEST: MAY CAUSE PAIN & INFLAMMATION OF MOUTH & DIGESTIVE SYSTEM, BURNS & PERFORATION OF ESOPHAGUS OR STOMACH, VOMIT, CIRCULATORY COLLAPSE, CONFUSI ON, DELIRIUM & COMA. CHRONIC: NO DATA. THE TOXICITY & CORROSIVITY OF SODIUM HYPOCHLORITE IS A FUNCTION OF (SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE: OBJECT IS TO FLUSH MATL OUT IMMED & THEN SEEK MED ATTN. IMMED FLUSH EYES W/DIRECTED STREAM OF WATER FOR AT LEAST 15 MIN WHILE FORCIBLY HOLDING EYELIDS APART TO ENSURE COMPLETE IRRIGATION OF ALL E YE & LID TISSUE. WASHING EYES W/IN ONE MIN IS ESSENTIAL TO ACHIEVE MAX EFTIVENESS. SEEK MED ATTN IMMED. SKIN: SEEK MED ATTN IMMED. FLUSH THOROUGHLY W/COOL WATER UNDER SHOWER WHILE REMOVING (ING 4) ===================== Fire Fighting Measures ===================== Extinguishing Media:USE WATER SPRAY, FOG, FOAM, DRY CHEMICAL OR CARBON DIOXIDE OR OTHER AGENTS SUITABLE FOR MATERIALS IN SURROUNDING FIRE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . ACID CONTAMINATION WILL PRODUCE VERY IRRITATING FUMES SIMILAR TO CHLORINE. Unusual Fire/Explosion Hazard:SODIUM HYPOCHLORITE SOLNS DECOMPOSE WHEN HEATED. DECOMP PRODS MAY CAUSE CNTNR TO RUPTURE OR EXPLODE. VIGOROUS RXN POSS W/ORG MATLS OR OXIDIZING AGENTS (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:DO NOT ALLOW SPILLED MATL TO ENTER SEWERS OR STREAMS. FLUSH W/WATER TO DILUTE AS MUCH AS POSSIBLE & PUMP INTO POLYETHYLENE CNTNRS FOR DISP. AVOID HEAT & CONTAM W/ACID MATLS. DO NOT USE COMBUST MATLS S UCH AS SAWDUST TO ABSORB HYPOCHLORITE. (ING 14) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE ADJACENT TO CHEMICALS THAT MAY REACT IF SPILLAGE OCCURS. COMPLY WITH DOT REGULATIONS WHEN SHIPPED. Other Precautions:IF CLOSED CNTNRS BECOME HEATED, VENT TO RELEASE DECOMP PRODS (MAINLY OXYGEN UNDER NORMAL DECOMP). DO NOT MIX OR CONTAMINATE W/AMMONIA, HYDROCARBONS, ACIDS, ALCOHOLS OR ETHERS. DO NOT REUSE CNTNRS: PRO D RESIDUES MAY REMAIN IN (ING 15) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATOR FOLLOWING MANUFACTURER'S RECOMMENDATIONS, SHOULD BE USED AS A PRECAUTIONARY MEASURE WHERE AIRBORNE CONTAMINANTS MAY OCCUR. Ventilation:PROVIDE GOOD GENERAL ROOM VENTILATION PLUS LOCAL EXHAUST AT POINTS OF EMISSION. Protective Gloves:IMPERVIOUS SUCH AS RUB/NEOPRENE/VINYL. Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 19) Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . WEAR IMPERVIOUS PROTECTIVE CLOTHING INCLUDING RUBBER SAFETY SHOES. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health BP: DECOMPOSES >230F,110C. PH: 12 @ 100 G/L. EXPLO HAZ: & MAY RSLT IN FIRE. EFTS OF OVEREXP: CONCENTRATION. INDUSTRIAL GRADES OF HIGHER CONCENTRATIONS THAN HOUSEHOLD BLEACH ARE MORE TOXIC & CORROSIVE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:SUPDAT Spec Gravity:1.27 (H*2O=1) pH:SUPDAT Solubility in Water:100% BY WT Appearance and Odor:COLORLESS TO LIGHT YELLOW-GREEN LIQUID WITH CHLORINE LIKE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTAMINATION WITH HEAVY METALS, REDUCING AGENTS, ORGANICS, ETHER, AMMONIA AND ACIDS. Stability Condition to Avoid:STRONG OXIDIZER, STABILITY DECREASES WITH CONCENTRATION, HEAT, LIGHT, DECREASE IN PH AND CONTAMINATION BY METALS. Hazardous Decomposition Products:ACID FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:REDUCE W/AGENTS SUCH AS BISULFITES OR FERROUS SALT SOLUTIONS. SOME HEAT WILL BE PRODUCED. KEEP ON ALKALINE SIDE & DILUTE W/COPIOUS AMOUNTS OF WATER. MAIN END-PRODUCT IS SALT WATER. COMPLY W/ALL APPLIC FEDERAL, STATE & LOCAL GOVERNMENT REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.