ALDON CORPORATION -- IODINE, LUGOL'S SOLUTION -- -
===================== Product Identification ===================== Product ID:IODINE, LUGOL'S SOLUTION MSDS Date:03/12/1999 FSC:NIIN:Submitter:D DG Status Code:A === Responsible Party === Company Name:ALDON CORPORATION Address:1533 W HENRIETTA RD City:AVON State:NY ZIP:14414-9508 Country:US Info Phone Num:716-226-6177 Emergency Phone Num:716-226-6177/800-424-9300 Resp. Party Other MSDS Num.:IX 150 Preparer's Name:MICHAEL RASZEJA Chemtrec Ind/Phone:(800)424-9300 CAGE:6V042 === Contractor Identification === Company Name:AL-DON CHEMICALS INC Address:1533 W HENRIETTA RD Box:City:AVON State:NY ZIP:14414-9508 Country:US Phone:716-226-6177 CAGE:6V042 Company Name:WARDS NATURAL SCIENCE ESTABLISHMENT INC Address:5100 W HENRIETTA RD Box:92912 City:ROCHESTER State:NY ZIP:14692-9012 Country:US Phone:(716) 359-2502 Contract Num:MDA414-00-P-5077 CAGE:63759 ============= Composition/Information on Ingredients ============= Ingred Name:IODINE CAS:7553-56-2 RTECS #:NN1575000 = Wt:4.74 OSHA PEL:C1 MG/M3;C0.1 PPM ACGIH STEL:C1.0 MG/M3;C0.1 PPM Ingred Name:POTASSIUM IODIDE CAS:7681-11-0 RTECS #:TT2975000 = Wt:7.23 Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 = Wt:88.03 ===================== Hazards Identification ===================== Health Hazards Acute and Chronic:CONTACT AS FUMES OR SOLUTION IS INTENSELY IRRITATING TO EYES, SKIN AND MUCOUS MEMBRANES. MAY CAUSE DELAYED LUNG INJURY. INGESTION: OF LARGE QUANTITIES CAUSE ABDOMINAL PAIN, VOMITING AND DIARRHEA. IN S EVERE CASES PURGING, EXCESSIVE THIRST, AND CIRCULATORY FAILURE MAY DEVELOP. Effects of Overexposure:CONTACT AS FUMES OR SOLUTION IS INTENSELY IRRITATING TO EYES, SKIN AND MUCOUS MEMBRANES. MAY CAUSE DELAYED LUNG INJURY. INGESTION: OF LARGE QUANTITIES CAUSE ABDOMINAL PAIN, VOMITING AND DIARRHEA. IN S EVERE CASES PURGING, EXCESSIVE THIRST AND CIRCULATORY FAILURE MAY DEVELOP. ======================= First Aid Measures ======================= First Aid:INGESTION: IF SWALLOWED, IF CONSCIOUS, GIVE ONE OR TWO GLASSES OF MILK, FOLLOWED BY A STARCH, FLOUR, OR EGG WHITE, AS A WATER SOLUTION. GET IMMEDIATE MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. EYES: FLUSH THOROUGHLY WITH WATER FOR 15 MINUTES, LIFTING UPPER AND LOWER EYELIDS OCCASIONALLY. GET IMMEDIATE MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR. IF BREATHING H AS STOPPED, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET IMMEDIATE MEDICAL ATTENTION. SKIN: FLUSH THOROUGHLY WITH WATER. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Lower Limits:NA Upper Limits:NA Extinguishing Media:USE ANY MEDIA SUITABLE FOR EXTINGUISHING SUPPORTING FIRE. Fire Fighting Procedures:IN FIRE CONDITIONS, WEAR A NIOSH/MSHA-APPROVED SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. USE FLOODING AMOUNTS OF WATER IN EARLY STAGES OF FIRE. Unusual Fire/Explosion Hazard:WHEN HEATED, EMITS TOXIC AND CORROSIVE, VIOLET IN COLOR, FUMES OF IODINE. IODINE IS CORROSIVE TO METALS AND TO ALL BODY TISSUES. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB SPILL WITH VERMICULITE, SAND, EARTH, PAPER TOWEL AND PLACE IN A SUITABLE CONTAINER FOR DISPOSAL. WASH FLOOR OR SPILL AREA WITH A 5-10% SODIUM THIOSULFATE SOLUTION. Neutralizing Agent:SODA ASH , SODIUM THIOSULFATE. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED AREA. REMOVE ALL CONTAMINATED CLOTHING AND SHOES. WASH BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. Other Precautions:READ LABEL ON CONTAINER BEFORE USING. DO NOT WEAR CONTACT LENSES WHEN WORKING WITH CHEMICALS. AVOID CONTACT WITH SKIN AND EYES. CONTACT WITH SKIN WILL LEAVE YELLOW IODINE STAIN. FOR LABORATORY USE ONL Y. NOT FOR DRUG, FOOD OR HOUSEHOLD USE. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED IN NORMAL LABORATORY HANDLING AT ROOM TEMPERATURE. IF NEEDED, WORK IN VENTILATION HOOD. Ventilation:LOCAL EXHAUST-RECOMMENDED. MECHANICAL(GENERAL)- RECOMMENDED. Protective Gloves:RUBBER. Eye Protection:CHEMICAL SAFETY GLASSES. Other Protective Equipment:SMOCK, APRON, EYE WASH STATION, GOGGLES, VENTILATION HOOD, PROPER GLOVES. Work Hygienic Practices:REMOVE ALL CONTAMINATED CLOTHING AND SHOES. WASH BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health WARDS PART #: 39-1685 ================== Physical/Chemical Properties ================== HCC:C3 Boiling Pt:=100.C, 212.F B.P. Text:APPROX. Melt/Freeze Pt:=0.C, 32.F M.P/F.P Text:MAY FREEZE @0C Vapor Pres:14(WATER) MM HG Vapor Density:0.7(WATER) Spec Gravity:1.0 Evaporation Rate & Reference:>1(ETHER=1) Solubility in Water:COMPLETE Appearance and Odor:DEEP-AMBER COLOR LIQUID; IODINE ODOR. Percent Volatiles by Volume:88.03% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONTACT OF GASEOUS AMMONIA OR ITS SOLUTIONS WITH FREE IODINE SHOULD BE AVOIDED TO PREVENT THE FORMATION OF THE EXPLOSIVE "NITROGEN IODIDE". ACETALDEHYDE, SODIUM AZIDE, SODIUM HYDRIDE. Stability Condition to Avoid:EXCESSIVE TEMPERATURE OR HEAT. Hazardous Decomposition Products:FREE IODINE. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information =================== Toxicological Information:THRESHOLD LIMIT VALUE: NONE ESTABLISHED FOR THIS SOLUTION. TOXICITY AS IODINE: ORAL HUMAN LDLO: 2000 MG/KG. WARNING! CORROSIVE! HARMFUL IF INHALED OR SWALLOWED. CAUSES IRRITATION TO SKIN, EYES, AND MU COUS MEMBRANES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE OR LOCAL LAWS. WORK IN VENTILATION HOOD. WEAR PROPER SAFETY EQUIPMENT, COLLECT WASTE IODINE IN LARGE BEAKER.COVER WITH LARGE VOLUME OF WATER. WHILE STIRRING, SLOWLY ADD SODA ASH OR SODIUM THOISULFATE UNTIL IODINE IS DISSOLVED AND SOLUTION IS COLORLESS. FLUSH TO SEWER WITH COPIOUS AMOUNTS OF WATER. =================== MSDS Transport Information =================== Transport Information:D.O.T.: NON-REGULATED. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.