FISHER SCIENTIFIC -- XYLENE -- 6810-01-119-8108
===================== Product Identification ===================== Product ID:XYLENE MSDS Date:06/30/1994 FSC:6810 NIIN:01-119-8108 === Responsible Party === Company Name:FISHER SCIENTIFIC Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-795-7100 Emergency Phone Num:201-795-7100;800-424-9300(CHEMTREC) CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:XYLENE (O-,M-,P- ISOMERS) (SARA 313) (CERCLA) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 83% OSHA PEL:100 PPM ACGIH TLV:100 PPM/150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYL BENZENE (SARA 313) CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 17% OSHA PEL:100 PPM ACGIH TLV:100 PPM/125 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SUPDAT:FROM AS FAR A DISTANCE AS POSSIBLE. KEEP UPWIND. RTECS #:9999999ZZ Ingred Name:EXPLO HAZ:ELECTRICAL CHARGES RESULTING IN SPARKS WITH POSSIBLE IGNITION. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP:200 PPM HAS CAUSED CONJ IRRIT. HIGHER CONCENTRATIONS, SEVERE IRRITATION, TEARING AND PHOTOPHOBIA.(ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:ETHYL BENZENE:IRRITATION @ 200 PPM, IRRITATION AND LACRIMATION >1000 PPM. (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:INGESTION:XYLENE:MAY CAUSE BURNING SENSATION IN MOUTH & STOMACH, SALIVATION, GASTROINTESTINAL DISTRESS, (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:NAUSEA, & TOXIC EFFECTS. 15-30 ML IS EXPECTED HUMAN LETHAL DOSE. WITH ASPIRATION INTO LUNGS, SEVERE (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:COUGH, DISTRESS, CHEM PNEUM, PULM EDEMA & HEMORR POSS. ETHYL BENZENE:MAY CAUSE ABDOM PAIN, NAUS, & VOMIT (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:WHICH MAY LEAD TO ASPIR W/EXTENSIVE EDEMA & HEMORR OF LUNG TISS. CHRONIC:INHAL:XYLENE:LIVER & KIDNEY DMG (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:POSS. ETHYL BENZENE:OVEREXPOSURE IN ANIMALS CAUSED UPPER RESP INFLAMMATION, NERVOUS SYSTEM DISORDERS, (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:AND CHANGES IN LIVER, KIDNEYS, BLOOD CHOLINESTERASE ACTIVITY. REPRODUCTIVE EFFECTS REPEATED IN (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:ANIMALS. SKIN:XYLENE:MAY CAUSE DEFATTING, DRYING, ERYTHEMA, CRACKING, THICKENING & BLISTERS. (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:ETHYL BENZENE:MAY CAUSE RASH/DERM. EYE:XYLENE:MAY CAUSE BURNING SENSATION, CONJ & BLURRED VISION. ETHYL (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:BENZENE:MAY CAUSE CONJ. INGEST:XYLENE:RPTD INGEST OF MIXED, META-,/PARA-ISOMERS BY PREGNANT MICE RSLTD IN(ING 16) RTECS #:9999999ZZ Ingred Name:ING 15:EFTS ON FERTILITY, ON EMBRYO/FETUS/SPECIFIC DEVELOPMENTAL ABNORM. ETHYL BENZENE:INGEST OF 408-680 MG/KG/ (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16:DAY FOR 182 DAYS BY RATS CAUSED SLIGHT LIVER & KIDNEY WT INCR W/SLIGHT PATHOLOGICAL SIGNS. FOR MORE (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:DETAILED HEALTH HAZARD INFORMATION CONTACT NEHC . RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:(@ LST 15 MINS). GET MED ATTN IMMED. INGEST:EXTREME CARE MUST BE USED TO PVNT ASPIR. GASTRIC (ING 20) RTECS #:9999999ZZ Ingred Name:ING 21:LAVAGE W/CUFFED ENDOTRACHEAL TUBE. TO PVNT FURTHER ASPIR IT SHOULD BE DONE W/IN 15 MIN. IN ABSENCE OF (ING 21) RTECS #:9999999ZZ Ingred Name:ING 20:DEPRESS/CONVULS/IMPAIRED GAG REFLEX, EMESIS CAN ALSO BE INDUCED USING IPECAC SYRUP. TREAT SYMPTOMATICALLY(ING 22) RTECS #:9999999ZZ Ingred Name:ING 21:AND SUPPORTIVELY. GASTRIC LAVAGE SHOULD BE PERFROMED BY QUALIFIED MED PERS. GET MED ATTN IMMED. RTECS #:9999999ZZ Ingred Name:SPILL PROC:HAZARD AREA. KEEP UNNEC PEOPLE AWAY, ISOLATE HAZARD AREA & RESTRICT ENTRY. REPORTABLE QTY (RQ) 1000 POUNDS. RTECS #:9999999ZZ Ingred Name:OTHER PREC:INSIDE STOR SHOULD BE IN STD FLAMM LIQS STOR ROOM/CABINET. STORE AWAY FROM INCOMPAT SUBSTANCES. (ING 25) RTECS #:9999999ZZ Ingred Name:ING 24:VAPS MAY BE EXPLO. AVOID OVERHEATING:CNTNRS MAY VIOLENTLY RUPTURE. AVOID CONTAMINTION OF WATER SOURCES. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORAL,RAT) 4300 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL:XYLENE:1000 PPM IDLH. UPPER RESP TRACT IRRITATION MAY OCCUR @ 200 PPM. HIGHER CONCS MAY CAUSE MORE SEVERE IRRIT & CNS DEPRESS. SIGNS & SYMPS MAY INCLUDE RESP DFCLTY, HEADACHE, NAUSEA, VOMI T, ABDOM PAIN, DIZZ, DROW, STAGG. ETHYLBENZENE:2000 PPM IDLH. MAY CAUSE SEV IRRIT OF NOSE & THROAT, (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:COUGH, FATG, DIZZ, HDCH, NARCOS, & COMA. DEATH POSS FROM RESP CTR PARALYSIS. SKIN:XYLENE:MAY CAUSE BURNING SENSATION, DRYING, ERYTHEMA, & BLISTERING. READILY ABSORBED. ETHYL BENZENE:LIQ/VAP M AY CAUSE IRRIT, INFLAMM, & POSSIBLY 1ST/2ND DEGREE BURNS. CAN BE ABSORBED & CAUSE SYSTEMIC TOX. EYE:XYLENE: (ING 5) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR IMMED. PERFORM ARTF RESP IF NEC. KEEP WARM & AT REST. TREAT SYMPTOMATICALLY & SUPPORTIVELY. GET MED ATTN IMMED. SKIN:REMOVE CONTAMD CLTH & SHOES IMMED. WASH W/SOAP & WATER UN TIL NO EVID OF CHEM REMAINS (@ LST 15-20 MINS). GET MED ATTN IMMED. EYE:WASH IMMED W/LG AMTS OF WATER/NORMAL SALINE, OCCASNLY LIFTING UPPER & LOWER LIDS, UNTIL NO EVID OF CHEM REMAINS (ING 19) ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:>81F,>27C Lower Limits:1.0% Upper Limits:7.0% Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR REGULAR FOAM. LARGER FIRES, USE WATER SPRAY, FOG OR REGULAR FOAM. Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . MOVE CNTNR FROM AREA IF CAN DO W/OUT RISK. APPLY WATER TO SIDES OF CNTNRS EXPOS TO FLAMES UNTIL WELL AFTER (SUPDAT) Unusual Fire/Explosion Hazard:DANGEROUS FIRE HAZ WHEN EXPOS TO HEAT/FLAME. VAP-AIR MIX ARE EXPLO ABOVE FL PT. VAPS ARE HVR/AIR & MAY TRAVEL CONSIDERABLE DIST TO SOURCE GENERATE (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:SHUT OFF IGNIT SOURCES. STOP LEAK IF CAN DO W/OUT RISK. USE WATER SPRAY TO REDUCE VAPS. SM SPILL-TAKE UP W/OTHER ABSORB MATL & PLACE INTO CNTNRS FOR LATER DISP. LARGER SPILLS-DIKE FAR AHEAD OF SPILL F OR LATER DISP. NO SMKNG, FLAMES/FLARES IN(ING 23) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:OBSERVE ALL FED, STATE, & LOC REGS WHEN STORING THIS SUBSTANCE. STORE I/A/W 29 CFR 1910.106. PROTECT AGAINST PHYSICAL DMG. Other Precautions:BONDING & GROUNDING:SUBSTANCES W/LOW ELECTROCONDUCTIVITY, WHICH MAY BE IGNITED BY ELECTROSTATIC SPKS, SHOULD BE STORED IN CNTNRS WHICH MEET BONDING & GROUNDING GUIDELINES SPECIFIED IN NFPA 77-1983. OU TSIDE/DETACHED STOR IS PREF. (ING 24) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESPS MUST BE NIOSH APPRVD. XYLENE:1000 PPM-ANY CHEM CARTRIDGE RESP W/ORG VAP CARTRIDGE(S). ANY POWERED AIR-PURIFYING RESP W/ORG VAP CARTRIDGE(S). ANY SUPPLIED-AIR RESP. ANY SCBA. CONT NEHC FOR MORE D ETAILED RESPIRATORY INFORMATION . Ventilation:PROVIDE LOC EXHAUST/GEN DILUTION VENT TO MEET PUBLISHED EXPOS LIMITS. VENT EQUIP SHOULD BE EXPLO-PROOF. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . APPROP PROT CLTHG & EQUIP TO PVNT SKIN CONTACT. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRE FIGHT PROC:FIRE IS OUT. STAY AWAY FROM ENDS OF TANKS. FOR MASSIVE FIRE IN CARGO AREA, USE UNMANNED HOSE HOLDER/MONITOR NOZZ; IF THIS IS IMPOSS, W/DRAW FROM AREA & LET FIRE BURN. ISOLATE FOR 1/2 M ILE IN ALL DIRECTIONS IF TANK, RAIL CAR/TANK TRUCK IS INVOLVED IN FIRE. USE WATER IN FLOODING AMTS AS FOG, APPLY (ING 3) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>279F,>137C Vapor Pres:6 @ 20C Vapor Density:3.7 Spec Gravity:0.86 Evaporation Rate & Reference:0.6 (BUTYL ACETATE =1) Solubility in Water:0.00003% Appearance and Odor:LIGHT COLORED OR COLORLESS MOBILE LIQUID WITH AN AROMTIC ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES XYLENE:OXIDIZERS(STRONG). ETHYL BENZENE:ACIDS(STRONG), BASES(STRONG), PLASTICS. FOR MORE MATLS TO AVOID CONT NEHC. Stability Condition to Avoid:AVOID CONT W/HEAT, SPKS, FLAMES, OR OTHER SOURCES OF IGNITION. Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE TOXIC OXIDES OF CARBON. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . DISP MUST BE I/A/W STDS APPLIC TO GENERATORS OF HAZARDOUS WASTE. EPA HAZARDOUS WASTE NUMBER U239. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.