MONSANTO CO -- ROUNDUP HERBICIDE  -- 6840-01-377-7113
<pre>=====================  Product Identification  =====================

Product ID:ROUNDUP HERBICIDE
MSDS Date:01/01/1994
FSC:6840
NIIN:01-377-7113
=== Responsible Party ===
Company Name:MONSANTO CO
Address:800 N LINDBERGH BLVD
City:ST LOUIS
State:MO
ZIP:63167
Country:US
Info Phone Num:314-694-6661
Emergency Phone Num:314-694-6661, CHEMTREC 800-424-9300
CAGE:76541
=== Contractor Identification ===
Company Name:EHRLICH J C CHEMICAL CO INC
Address:500 SPRING RIDGE DR
Box:City:READING
State:PA
ZIP:19612-3848
Country:US
Phone:610-372-9700/FAX: 610-378-9744
CAGE:8C885
Company Name:MONSANTO COMPANY
Address:800 N LINDBERGH BLVD
Box:City:SAINT LOUIS
State:MO
ZIP:63167
Country:US
Phone:314-694-6661 OR 800-332-3111
CAGE:76541

=============  Composition/Information on Ingredients  =============

Ingred Name:ETHOXYLATED TALLOWAMINES
CAS:61791-26-2
RTECS #:WW3150000
Other REC Limits:NONE RECOMMENDED

Ingred Name:GLYSOPHOSATE, (ISOPROPYL AMMINE SALT OF N-PHOSPHONOMETHYL
    GLCYNE)
CAS:1071-83-6
RTECS #:MC1075000
Fraction by Wt: 41.0%
Other REC Limits:NONE RECOMMENDED

Ingred Name:INERT INGREDIENTS
Fraction by Wt: 59.0%
Other REC Limits:NONE RECOMMENDED

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50 ORAL RAT >5000MG/KG.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:NO
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:EYES:CAUSES PAIN,RENESS & TEARING
    BASED ON TOXICITY STUDIES. SKIN/INHAL/INGEST:NO MORE THAN SLIGHTLY
    TOXIC & NO MORE THAN SLIGHTLY IRRIT BASED ON TOXICITY STUDIES. NO
    SIGNIFICANT ADVERSE HEALTH EFFECT S EXPECTED IF ONLY SM
    AMTS(<MOUTHFUL)ARE INGESTED. INGEST OF SIMILAR FORMULATIONS
    PRODUCES GI DISCOMFORT & (SUPPLEMENTA)
Effects of Overexposure:EYE PAIN, REDNESS, TEARING. LG AMTS INGESTED
    CAUSES GASTROINTESTINAL DISCOMFORT, IRRIT OF MOUTH, NAUSEA,
    VOMITING, DIARRHEA, HYPOTENSIN, LUNG EDEMA.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:SKIN:REMOVE CONTAMIN CLOTHING. WASH AREA WELL W/SOAP/WATER.
    EYES:IMMED HOLD EYELIDS OPEN & FLUSH W/PLENTY OF WATER. GET MED
    ATTN. INGEST:IMMED DILUTE BY SWALLOWING WATER OR MILK. GET MED
    ATTN. INHAL:R EMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARAT RESP
    PREFERABLY MOUTH-TO-MOUTH. GET MED ATTN. NOTE:FOR ADDTN HUMAN
    EMERGENCY FIRST AID OR TREATMENT GUIDANCE CALL COLLECT ANYTIME
    DAY/NIGHT 314-694-4000.

=====================  Fire Fighting Measures  =====================

Flash Point Method:PMCC
Flash Point:>200F,>93C
Extinguishing Media:WATER SPRAY, FOAM, DRY CHEMICAL, CO2, OR ANY CLASS
    B EXTINGUISHING AGENT.
Fire Fighting Procedures:FIREFIGHTER/OTHERS THAT MAY BE EXPO TO
    VAP/MIST/PROD OF COMBUSTION SHOULD WEAR FULL PROT CLOTHING & SCBA.
    EQMPT SHOULD BE THOROUGHLY CLEANED AFTER USE.
Unusual Fire/Explosion Hazard:NONE.

==================  Accidental Release Measures  ==================

Spill Release Procedures:SM:SOAKUP W/TOWELS/ABSORBENT MATL.DISCARD IN
    TRASH.CLEAN AREA W/SOAP/WATER & RINSE.LG:DIKE.ABSORB
    W/ATTAPULGITE/BENTONITE/ABSORBENT CLAYS.COLLECT/PLACE IN
    DRUM/DISPOSE.SCRUB WELL AREA W/STRG INDUSTRIA L DETERGENT &
    RINSE.DUG UP IF GROUND ABSORBED.

======================	Handling and Storage  ======================

Handling and Storage Precautions:DO NOT GET IN EYES/ON CLOTH.AVOID
    BREATH VAP/SPRAY MIST.DO NOT APPLY DIRECTLY TO H2O/AREAS WHERE
    SURFACE H2O PRESENT/INTERTIDAL AREAS BEL MEAN HI MARK
Other Precautions:DO NOT CONTAMIN H2O WHEN DISPOSING EQMPT
    WASHWATERS.DO NOT CONTAMIN H2O/FOODSTUFFS/FEED/SEED BY
    STORAGE/DISPOSAL.EMPTIED CNTNR RETAIN VAP/RESIDUE.OBSERVE ALL
    LABELED SAFEGUARDS TIL CNTNR IS CLEAN/RECO
    NDITION/DESTROYED.REFORMULATION PROHIBIT

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:HANDLING UNDIL PROD:IN EVENT OF ACCIDENTAL MATL
    DISCHARGE DURING MFG/HANDLING PRODUCING HEAVY VAP/MIST USE
    NIOSH/MSHA APPROV EQMPT.FULLFACE RESP W/PURIFYING ELEMENTS AGAINST
    ORG VAP/DUST/MIST FOR PEST ICIDES.CARTRIDGES:TC-23C,CANISTER:TC-14G
Ventilation:NO SPECIAL PRECAUTIONS ARE RECOMMENDED.
Protective Gloves:RECOMMENDED.
Eye Protection:CHEM SPLASH GOGGLES
Other Protective Equipment:APROPRIATE PROT CLOTH TO PREVENT SKIN
    CONTACT.LONG-SLEEVED SHIRT/LONG PANTS/SHOES/SOCKS/PROT EYEWEAR.
Work Hygienic Practices:WASH HANDS BEFORE EAT/DRINK/CHEW GUM/USE
    TOBACCO/TOILET.WASH WELL CONTAMIN CLOTH.FLLOW MFG INSTRUC ON
    CLEAN/MAINTAIN PPE
Supplemental Safety and Health
HEALTH HAZ:IRRIT OF MOUTH, NAUSEA, VOMITING, DIARR. ORAL INGEST OF LG
    AMTS REPORTED TO RESULT IN HYPOTENSION & LUNG EDEMA. RESP
    PROT:FULLFACEPIECE REPLACES NEED FOR CHEM GOGG.COMPLY W/OSHA
    29CFR1910.1 34.APPLICATION OF DIL PROD:RESP NOT REQUIRED.

==================  Physical/Chemical Properties  ==================

HCC:T5
Spec Gravity:1.17
pH:4.7,1%
Appearance and Odor:CLEAR,VISCOUS AMBER-COLORED SOLUTION,PRACTICALLY
    ODORLESS-SLIGHT AMINE LIKE ODO

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
REACTS W/GALVANIZED OR UNLINED STEEL CNTNRS TO PRODUCE FLAMM HYDROGEN
    GAS.RX W/CAUSTIC(BASIC)MATL TO LIBERATE HEAT.
Stability Condition to Avoid:STABLE FOR @LEAST 5YRS UNDER NORMAL
    CONDITIONS OF WAREHOUSE STORAGE. CONDTN TO AVOID:NONE.
Hazardous Decomposition Products:NONE.

====================  Disposal Considerations  ====================

Waste Disposal Methods:WASTE FROM USE OF PROD THAT CANNOT BE
    USED/CHEMICALLY REPORCESSED SHOULD BE DISPOSED OF IN LANDFILL
    APPROVED FOR PESTICIDE DISPOSAL OR IAW APPLLICABLE FED/STATE/LOC
    PROCEDURES. EPA REG #:524-445.

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