SCOTT SPECIALTY GASES -- TRICHLOROFLUOROMETHANE -- 6830-01-040-3656
===================== Product Identification ===================== Product ID:TRICHLOROFLUOROMETHANE MSDS Date:10/16/1997 FSC:6830 NIIN:01-040-3656 Status Code:A === Responsible Party === Company Name:SCOTT SPECIALTY GASES Address:6141 EASTON RD City:PLUMSTEADVILLE State:PA ZIP:18949-0310 Country:US Info Phone Num:215-766-8861 Emergency Phone Num:215-766-8861 Resp. Party Other MSDS Num.:75-69-4/E-1 CAGE:51847 === Contractor Identification === Company Name:SCOTT SPECIALTY GASES Address:6141 EASTON RD (6141 ROUTE 611) Box:310 City:PLUMSTEADVILLE State:PA ZIP:18934 Country:US Phone:215-766-8861/ FAX: 215-766-0416 Contract Num:N00406-98-M-Q646 CAGE:51847 ============= Composition/Information on Ingredients ============= Ingred Name:TRICHLOROFLUOROMETHANE; (OTHER STEL 1000 C ( MFR)) CAS:75-69-4 RTECS #:PB6125000 > Wt:99. Other REC Limits:MAC 1000 PPM (MFR) OSHA PEL:5600 MG/M3;1000 PPM ACGIH STEL:C5620 MG/M3 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ozone Depleting Chemical:1 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: CHLOROFLUOROCARBON (CFC) MATLS HAVE PRDCED SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR EFT IN HUMANS. ADRENOMIMETICS (E.G.,EPINEPHRINE) MAY BE CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY/CHRONICALLY EXPOSED TO CFC'S . INHAL MAY CAUSE ASPHY DUE TO DILUTION OF AVAIL OXYG IN AIR. SYMPS INCLUDE RAPID RESP, MUSCULAR INCOOR, FATIGUE, NAUS, V OMITING & UNCON. SKIN CONTACT MAY CAUSE DEFATTING OF TISSUE. VAPORS HAVE LITTLEEFFECT ON EYES. PRESS DROP THRU VALVES & PIPING MAY CAUSE EXTREME COLD & FROSTBITE ON CONTACT. CHRONIC: EYES, LUNG & LIVE R DAMAGE. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:INHALATION: IMMEDIATELY REMOVE VICTIM TO FRESH AIR. IF BREATHING HAS STOPPED, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. EYE CONTACT: IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SKINCONTACT: IF FROSTBITE OCCURS, FLUSH AFFECTED AREAS WITH LUKEWARM WATER. INGESTION: NONE. IN EVENT OF EXPOSURE, CONSULT A PHYSICIAN. NOTE TO PHYSICIAN: MONITO R ARTERIAL BLOOD GASES, ENG, AND VITAL SIGNS. DILANTIN IMPROVES ARTRIO-VENTRICULAR CONDUCTION AND MAY BE USEFUL IN THE MANAGEMENT OF VENTRICULAR ARRYTHMIAS. ===================== Fire Fighting Measures ===================== Flash Point:NON FLAMMABLE Extinguishing Media:USE WHAT IS APPROPIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:USE NIOSH APPROVED PRESSURE DEMAND SCBA AND FULL PROTECTIVE EQUIPMENT . KEEP FIRE EXPOSED CYLINDERS COOL WITH WATER SPRAY. Unusual Fire/Explosion Hazard:CYLINDER RUPTURE MAY OCCUR UNDER FIRE CONDITIONS. THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE CHLORIDES, FLUORIDES AND PHOSGENE . ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP PROCEDURES: EVACUATE AND VENTILATE AREA. SHUT OFF SOURCE IF POSSIBLE AND REMOVE SOURCE OF HEAT. TRY TO PREVENT RELEASE TO THE ATMOSPHERE DUE TO POTENTIAL DECOMPOSITION OF OZONE IN THE ATMO SPHERE. SPECIALIZED EQUIPMENT: NONE. ====================== Handling and Storage ====================== Handling and Storage Precautions:PRECAUTIONS TO BE TAKEN IN HANDLING: SECURE CYLINDER WHEN USING TO PROTECT FROM FALLING. USE SUITABLE HAND TRUCK TO MOVE CYLINDERS. PRECAUTIONS TO BE TAKEN IN STORAGE: STORE IN WELL VENTILATED AREA S. KEEP VALVE PROTECTION CAP ON CYLINDERS WHEN NOT IN USE. Other Precautions:PROTECT CONTAINERS FROM PHYSICAL DAMAGE. DO NOT DEFACE CYLINDERS OR LABELS. CYLINDERS SHOULD BE REFILLED BY QUALIFIED PRODUCERS OF COMPRRESSED GAS. SHIPMENT OF A COMPRESSED GAS CYLINDER WHICH HAS N OT BEEN FILLED BY THE OWNER OR WITH HISWRITTEN CONSENT IS A VIOLATION OF FEDERAL LAW (49 CFR). ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN CASE OF LEAKAGE, USE (NIOSH APPROVED) SELF-CONTAINED BREATHING APPARATUS. Ventilation:PROVIDE ADEQUATE GENERAL & LOCAL EXHAUST VENT TO MAINTAIN CONCENTRATION BELOW EXPOSURE LIMITS. Protective Gloves:PROTECTIVE GLOVES TO PREVENT CONTACT WITH COLD EQUIPMENT. Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES . Other Protective Equipment:SAFETY SHOES WHEN HANDLING CYLINDERS. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:=23.7C, 74.8F Vapor Pres:@ 25 DEG C: 796 MM HG Vapor Density:5.0 AIR=1 Spec Gravity:GAS (H20=1) Evaporation Rate & Reference:GAS Solubility in Water:INSOLUBLE. Appearance and Odor:COLORLESS GAS WITH SLIGHT ETHEREAL ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI AND ALKALINE EARTH MATERIALS. MG AND AL MAY ALSO BE REACTIVE. Stability Condition to Avoid:STORAGE IN POORLY VENTILATED AREAS. STORAGE NEAR A HEAT SOURCE. Hazardous Decomposition Products:CHLORIDES AND FLUORIDES. CARBONYL HALIDES. PHOSGENE. =================== Toxicological Information =================== Toxicological Information:LETHAL CONCENTRATION (LC50): 104,800 PPM, RAT 1 HOUR. LETHAL DOSE 50 (LD50): N/AP. TERATOGENICITY: N/AP. REPRODUCTIVE EFFECTS: N/AP. MUTAGENICITY: N/AP. ===================== Ecological Information ===================== Ecological:THIS MATERIAL IS A CLASS 1 OZONE DEPLETING MATERIAL. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE DISPOSAL METHOD: DISPOSE OF NON-REFILLABLE CYLINDERS IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. ALLOW GAS TO VENT SLOWLY TO ATMOSPHERE IN AN UNCONFINED AREA OR EXHAUST HOOD. IF T HE CYLINDERS ARE THE REFILLABLE TYPE, RETURN CYLINDERS TO SUPPLIER W/ ANY VALVE OUTLET PLUGS/CAPS SE CURED & VALVE PROTECTION CAPS IN PLACE. =================== MSDS Transport Information =================== Transport Information:CONCENTRATION: 99+%. DOT DESCRIPTION (US ONLY): PROPER SHIPPING NAME: TRIFLUOROMETHANE. HAZARD CLASS: 2.2 (NONFLAMMABLE). IDENTIFICATION NUMBER: UN1984. REPORTABLE QUANTITIES: NONE. LABELING: NONFLAMMABLE GAS. ADR/RID (EU ONLY):CLASS 2, 2A. SPECIAL PRECAUTIONS: CYLINDERS SHOULD BE TRANSPORTED IN A SECURE UPRIGHT POSITION IN WELL VENTILATED TRUCK. ===================== Regulatory Information ===================== SARA Title III Information:SARA: THE THRESHOLD PLANNING QUANTITY FOR MATERIAL IS 10,000 LBS. Federal Regulatory Information:OSHA: PROCESS SAFETY MANAGEMENT: MATERIAL IS NOT LISTED IN APPENDIX A OF 29 CFR 1910.119 AS HIGHLY HAZARDOUS CHEMICAL. TSCA: MATERIAL IS LISTED IN TSCA INVENTORY. EU NUMBER: 200-902-6. NUMBER IN ANNEX 1 OF DIR 67/548: NOT LISTED IN ANNEX 1. EU CLASSIFICATION: N/AV. R:N/AV. S: N/AV. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.